THIOPHENE MONOMERS OR OLIGOMERS

Due to extended pi-electron cloud overlaps, organometallic molecules or aromatic oligometers such as anthracene exhibit semiconductor properties. Conductive polymers have extended delocalized bonds that creates electrical conductivity when charge carriers generated make positive charges (holes) and negative charges (electrons) move to opposite electrodes. Doping is the intentional impurities in a pure semiconductor to generate charge carriers. The transportation of charges is responsible for fluorescence and electrical energy. These can form well-ordered thin crystalline films. Organic semiconductors have some merits of self radiation, flexibility, light weight, easy fabrication, and low cost. Organic electroluminescence materials have lead to the rapid development of photovoltaic and display devices such as organic solar cells, biosensitizers, OLED(Organic Light Emiting Diode), OTFT(Organic Thin Film Transistor), Wearable Display, and e-Paper. Some examples of organic electroluminescence materials are:

  • Oligomer Electro Luminescence Materials
    • 8-hydroxyquinoline aluminum
    • Anthracene
    • Pentacene
    • Penyl substituent cyclopentadiene derivatives
    • Phthaloperinone derivatives
    • Perylene derivatives
    • Rubrene
  • Polymer Electro Luminescence Materials
    • Polyanilines
    • Poly(p-phenylenevinylene)s
    • Poly(thiophene)s
    • Poly(alkylfluorene)s
    • Poly(acetylene)s
  • Oligomer Electro Luminescence Materials
    • 8-hydroxyquinoline aluminum
    • Anthracene
    • Pentacene
    • Penyl substituent cyclopentadiene derivatives
    • Phthaloperinone derivatives
    • Perylene derivatives
    • Rubrene
  • Polymer Electro Luminescence Materials
    • Poly(p-phenylene) and its derivatives
    • Poly(p-phenylenevinylene) and its derivatives
    • Polythiophene and its derivatives
    • Poly(alkylfluorene) and its derivatives

THIOPHENE MONOMERS OR OLIGOMERS

THIOPHENE

CAS #

FORMULA

MOL WT.

MELTING POINT

BOILING POINT
2-Thienylboronic acid; Thiophene-2-boronic acid 6165-68-0 C4H5BO2S 127.96

138 - 140 C

 
5-Methyl-2-thiopheneboronic acid 162607-20-7 C5H7BO2S 141.98

161- 165 C

 
3,4-Ethylenedioxyl thiophene

126213-50-1

 C6H6O2S 142.18 10 - 11 C 193 C

2,2'-Bithienyl; 2,2'-Dithienyl

492-97-7

 C8H6S2 166.26

32 - 33 C

260 C

 2,2':5',2'-Terthiophene; 2,2':5',2-Terthienyl; 2,5-thiophenyl-thiophene; Alpha-terthienyl; terthiophene

1081-34-1

 C12H8S3 248.39

93 - 95 C

 
3,2':5',3"-Terthiophene

81294-16-8

 C12H8S3 248.39

175 - 181 C

 
5-Hexyl-2,2'-bithiophene

173448-31-2

 C14H18S2 250.42

 

355 C
3,4-Dihydroxythiophene-2,5-dicarboxylic acid diethyl ester 1822-66-8 C10H12O6S 260.26

 

153 C
2,5-Dibromo-3-butylthiophene 116971-10-9 C8H10Br2S 298.04

 

270 - 280 C
3,4-Dihydroxy-thiophene-2,5-dicarboxylic acid diethyl ether disodium salt   14282-56-5 C10H10Na2O6S 304.23

320 - 324 C

 
2,5-Dibromo-3-phenylthiophene 19698-46-5 C10H6Br2S 318.03

35 - 39 C

 
5,5'-Dibromo-2,2'-bithiophene 4805-22-5 C8H4Br2S2 324.06 144 -146 C

 
2,5-Dibromo-3-cyclohexylthiophene 302912-44-3 C10H12Br2S 324.08

296 C

 
2,5-Dibromo-3-hexylthiophene 116971-11-0 C10H14Br2S 326.09

 

 
2,2',5',2'',5'',2'''-Quaterthiophene; alpha-Quarterthienyl; 4T

5632-29-1

 C16H10S4 330.51

211 - 214 C

 
2,5-Dibromo-3-octylthiophene 149703-84-4 C12H18Br2S 354.14

 

316 C
2,5-Dibromo-3-decylthiophene 158956-23-1 C14H22Br2S 382.20

 

168 - 170 at 2 mmHg
2,5-Dibromo-3-dodecylthiophene 148256-63-7 C16H26Br2S 410.25

 

 135 C at 2.5 mmHg
Sexithiophene; 6T

88493-55-4

 C24H14S6 494.76

290 C